Iron colloids/organic matter associated transport of major and trace elements in small boreal rivers and their estuaries (NW Russia)     

O. S. Pokrovsky  J. Schott 《Chemical Geology》2002,190(1-4):141-179

The chemical status of major and trace elements (TE) in various boreal small rivers and watershed has been investigated along a 1500-km transect of NW Russia. Samples were filtered in the field through a progressively decreasing pore size (5, 0.8 and 0.22 μm; 100, 10, and 1 kD) using a frontal filtration technique. All major and trace elements and organic carbon (OC) were measured in filtrates and ultrafiltrates. Most rivers exhibit high concentration of dissolved iron (0.2–4 mg/l), OC (10–30 mg/l) and significant amounts of trace elements usually considered as immobile in weathering processes (Ti, Zr, Th, Al, Ga, Y, REE, V, Pb). In (ultra)filtrates, Fe and OC are poorly correlated: iron concentration gradually decreases upon filtration from 5 μm to 1 kD whereas the major part of OC is concentrated in the <1–10 kD fraction. This reveals the presence of two pools of colloids composed of organic-rich and Fe-rich particles. According to their behavior during filtration and association with these two types of colloids, three groups of elements can be distinguished: (i) species that are not affected by ultrafiltration and are present in the form of true dissolved inorganic species (Ca, Mg, Li, Na, K, Sr, Ba, Rb, Cs, Si, B, As, Sb, Mo) or weak organic complexes (Ca, Mg, Sr, Ba), (ii) elements present in the fraction smaller than 1–10 kD prone to form inorganic or organic complexes (Mn, Co, Ni, Zn, Cu, Cd, and, for some rivers, Pb, Cr, Y, HREE, U), and (iii) elements strongly associated with colloidal iron in all ultrafiltrates (P, Al, Ga, REE, Pb, V, Cr, W, Ti, Ge, Zr, Th, U). Based on size fractionation results and taking into account the nominal pore size for membranes, an estimation of the effective surface area of Fe colloids was performed. Although the total amount of available surface sites on iron colloids (i.e., 1–10 μM) is enough to accommodate the nanomolar concentrations of dissolved trace elements, very poor correlation between TE and surface sites concentrations was observed in filtrates and ultrafiltrates. This strongly suggests a preferential transport of TE as coprecipitates with iron oxy(hydr)oxides. These colloids can be formed on redox boundaries by precipitation of Fe(III) from inflowing Fe(II)/TE-rich anoxic ground waters when they meet well-oxygenated surface waters. Dissolved organic matter stabilizes these colloids and prevents their aggregation and coagulation. Estuarine behavior of several trace elements was studied for two small iron- and organic-rich rivers. While Si, Sr, Ba, Rb, and Cs show a clear conservative behavior during mixing of freshwaters with the White sea, Al, Pb and REE are scavenged with iron during coagulation of Fe hydroxide colloids.  相似文献   

Study on Paleoenvironment since Late Glacial Eooch in Lanzhou Area, China     

Yang Guifang  Yin Hongfu  Li ChangAn 《中国地质大学学报(英文版)》2002,13(1)

The Hongzuisi Section in Lanzhou area is used to infer the paleoclimate since the late glacial epoch. Through combined analysis of organic carbon isotope and CaCO3 content, paleoenvironment evolution of Hongzuisi Section since the late glacial epoch is discussed. There were changes in both drymoist and warm-cold. Especially the climate changes can be compared with synchronous sections of other areas, which provides useful information for our future forecast.  相似文献   

Phototransformation of aromatic pollutants in solar light: Photolysis versus photosensitized reactions under natural water conditions   总被引：3，自引：0，他引：3  

Delphine Vialaton  Claire Richard 《Aquatic Sciences - Research Across Boundaries》2002,64(2):207-215

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中国耕地有机质含量变化对土地生产力影响的定量研究   总被引：23，自引：6，他引：23  

王卫  李秀彬 《地理科学》2002,22(1):24-28

在土地持续利用与管理研究中，土地质量变化对土地生产力影响的定量研究是核心内容之一。借助新古典经济学的生产函数法，构建了我国耕地的生产函数模型，定量模拟了我国耕地有机质含量变化的边际产出率性和边际生产力。初步结果表明，由于我国长期存在耕过度利用导致有机质含量及肥力下降问题，当前提高耕地质量的增产潜力十分可观。  相似文献   

Total N,total P and organic matters content in floodplain soils of Xianghai Nature Reserve     

Deng Wei  Zhai Jin-liang  He Yan 《地理学报(英文版)》2002,12(1):58-64

Soil sediment samples of 10 layers with a spacing of 10 cm each were collected in different floodplain zones adjacent to Huolin River in the Xianghai Nature Reserve, and contents of total N, total P and organic matters were analyzed. The results showed that contents of total N, total P and organic matters were generally decreasing with the increase of distance from sample locations to the river channel, and contents of the three items were generally higher in the upper soil layer than that in the lower soil layer. The content variations displayed how flooding functions influenced nutrient matter content variations in floodplain soils since the flood inundation frequencies of the sample locations varied. The correlation analysis displayed that there were remarkable relativities between total N, total P and organic matters within definite spatial distance from the Huolin River channel.  相似文献   

Floodplain–river ecosystems: lateral connections and the implications of human interference     

Martin C. Thoms   《Geomorphology》2003,56(3-4):335

Floodplains are ecotones that form a transition between aquatic and terrestrial environments. These important ecosystems can be described as dynamic spatial mosaics in which water plays an important role in connecting various patches on the floodplain surface. Hydrological connections facilitate the exchange of carbon and nutrients between the river channel and the floodplain and therefore influence the productivity of the entire river system. This paper examines the influence of hydrological connections on the potential exchange of dissolved organic carbon between a large Australian floodplain to a river channel, and the effects of land and water developments on these exchanges. The paper proposes that an understanding of floodplain ecosystems requires an interdisciplinary approach—a recognition of the importance of the three disciplines hydrology, geomorphology and ecology. Large-scale water-resources and floodplain development has significantly altered the spatial and temporal patterns of hydrological characteristics in the Lower Balonne floodplain, Australia. The magnitude, frequency and duration of flooding events have all been reduced. The construction of levees and water storages has also reduced the reactive floodplain surface area. The presented data show the impacts of these changes on the potential supply of dissolved organic carbon from the floodplain surface during periods of inundation. Annual reductions of up to 1293 tonnes of dissolved organic carbon supply were noted and reductions were especially significant for floods with an average recurrence interval of 2 years or less. Some small flood events no longer facilitate the potential supply of dissolved organic carbon from the floodplain to the river channel because of water-resources and floodplain developments.  相似文献   

剥片高岭土的有机改性   总被引：12，自引：0，他引：12  

孙红  刘志强  单永奎  何鸣元 《矿物学报》2003,23(2):97-101

用醋酸钾进行插层形成高岭土—醋酸钾复合体。通过X射线检测，高岭土层间距明显增大。将此复合体通过水洗，除去醋酸钾，高岭土即被剥片。剥片后高岭土粒径变小，但保持了高岭土的基本层状结构。用偶联剂对剥片后高岭土进行有机改性，形成高岭土有机复合物。“有效活化指数”的测定实验表明，利用此种方法制备的剥片高岭土有机改性效果很好。  相似文献   

岩体可爆性分级物元分析模型及其应用   总被引：4，自引：0，他引：4  

程绪涛  冯玉国 《地质灾害与环境保护》2003,14(2):57-59

首次提出用物元分析进行岩体可爆性分级的新方法。该模型将岩体可爆性类别、分类指标及其特征值作为物元，根据岩体可爆性分级标准建立关联函数，通过计算综合关联度判断岩体可爆性类别，用实例与其他方法进行了对比，得到一致的结果。该方法计算简便、分类合理，实用性强。  相似文献   

The Role of Organic Matter During Metal Enrichment in Permian Kupferschiefer of the Rudna Mine,Southwest Poland     

孙玉壮  WILHELM PüTTMANN 《中国地球化学学报》2003,22(1):1-10

The bulk composition of organic matter and saturated and aromatic hydrocarbons extracted from 16 samples collected from two Kuperschiefer profiles in the Rudna mine,Southwest Poland has been analyzed to study the role of organic matter during base metal enrichment in the Kupferschiefer shale.The results indicated that the extract yields and saturated hydrocarbon yields decreased with increasing base metal contents.GC and GC/MS analyses indicated that n -alkanes and alkylated aromatic compounds were depleted and may have served as hydrogen donators for thermochemical sulfate reduction.The enrichment of base metal is closely connected with the destruction of hydrocarbons.  相似文献   

碳酸盐岩中有机质组成特征分析   总被引：2，自引：0，他引：2  

王敏芳 《世界地质》2003,22(1):26-29

对碳酸盐岩有机质组分进行分类时，有两种分类标准，一是主要采用煤岩学方法，二是采用孢粉学研究方法。本文使用煤岩学方法作为标准，对碳酸盐岩有机质的组成特征进行分析。按有机质来源和有机组分光性和形态等方面差别划分为内源有机质、次生有机质和陆源有机质三类。内源有机质类中分腐泥组和动物有机组，前者主要来源于菌藻类，后者则主要来源于浮游动物有机体；次生有机质中区分出微粒体、有机包裹体、沥青；陆源有机质类分类术语仍沿用煤显微组分分类系统和术语。碳酸盐岩烃源岩的有机质主要为腐泥型，有机质来源以低等藻类为主，且有机质组成特征与碳酸盐岩烃源岩的地质年代有关。碳酸盐岩还存在着差异演化的特征。  相似文献